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Updated: May 19, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

アルキンがCpCr(CO) 3Hと反応するメカニズム. ラジカルサイクライゼーションへの適用

Deven P Estes1, Jack R Norton, Steffen Jockusch

  • 1Department of Chemistry, Columbia University, 3000 Broadway, New York, New York 10027, USA.

Journal of the American Chemical Society
|August 21, 2012
PubMed
まとめ

本研究では,活性化されたアルキンとCpCr (CO) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H) (H)) の反応を調査し,水素化および循環化反応における水素原子移転 (HAT) と単一の電子移転 (SET) といった明確なメカニズムを明らかにした.

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[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst09:12

[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

Introduction
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Preparation of Alkynes: Alkylation Reaction

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Preparation of Alkynes: Dehydrohalogenation

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