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Updated: May 19, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
19:58

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

アルキルブロミドの脱水ハロゲン化のための軽度な,パラジウム触媒化された方法:合成と機械学的研究

Alex C Bissember1, Anna Levina, Gregory C Fu

  • 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

Journal of the American Chemical Society
|August 22, 2012
PubMed
まとめ

この研究では,β-ヒドリド除去をパラジアム触媒による脱水ハロゲン化に使用し,室温でのアルキルブロミドから端末オレフィンを効率的に生成します. この新しい方法は, (R) - メバロノラクトンの合成に成功裏に適用されました.

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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

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