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Updated: May 18, 2026

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
12:30

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework

Published on: April 9, 2018

ラジカルディチオレンとディセレノレン黄金複合体に基づく単成分分子金属におけるアニゾトロプ的化学圧力効果

Gilles Yzambart1, Nathalie Bellec, Ghassan Nasser

  • 1Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes 1, Matière Condensée et Systèmes Electroactifs, Campus de Beaulieu, Bât 10A, 35042 Rennes cedex, France.

Journal of the American Chemical Society
|September 27, 2012
PubMed
まとめ

研究者は,単一コンポーネントの導体のための新しい金複合体を開発しました. 硫黄をセレニウムに置き換えることで伝導性が著しく増加し,酸素の置換により伝導性が低下し,材料の特性や圧力効果についての洞察を提供した.

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Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene09:45

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
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