関連する実験動画
Updated: May 17, 2026

07:03
Measuring Magnetically-Tuned Ferroelectric Polarization in Liquid Crystals
Published on: August 15, 2018
可能な分子ベースのマルチフェロイン:トリエチルメチラモニウムテトラブロモフェラート (III) の室温以上の磁気流電結合です
Hong-Ling Cai1, Yi Zhang, Da-Wei Fu
1Ordered Matter Science Research Center, Southeast University, Nanjing, PR China.
Journal of the American Chemical Society
|October 31, 2012
まとめ
新しい分子マルチフェロ材料であるトライエチルメチラモニウムテトラブロモフェラート (III) は,室温以上で鉄電気および磁気移行を示す. これは,高度な電子アプリケーションの重要な特性である重要な磁気電気結合につながります.
科学分野:
- マテリアルサイエンス 材料科学
- 固体物理 固体物理学
- 化学 化学は化学です.
背景:
- 同時に鉄電気と磁気による秩序を呈するマルチフェロ材料は,新しい電子機器にとって非常に興味深いものです.
- 室温に近い相変化を持つ材料を発見することは,実用的な応用において極めて重要です.
- 分子マルチフェロインは,調性および加工において潜在的な利点を提供します.
研究 の 目的:
- 新しい分子マルチフェロ材料の発見を報告するために.
- トライエチルメチラモニウムテトラブロモフェラート (TETRABROMOFERATE) の鉄電気および磁気特性を調査する.
- 材料の磁気流電結合と相変遷を特徴付けるため.
主な方法:
- トライエチルメチラモニウムテトラブロモフェラート (III) の合成と特徴づけ
- 温度に依存する介電および磁気測定.
- 段階移行の行動と磁気流電反応の分析.
主要な成果:
- 室温以上の分子マルチフェロイド,トリエチルメチラモニウムテトラブロモフェラート (III) (1) が発見されました.
- 鉄電気と磁気相変遷は360K近くで発生し,強力な磁気流電結合 (0.6MHzで18%) を示しています.
- 171 Kの低温の鉄電-鉄電の移行が観測され,わずかな磁気および介電的異常が観察されました.
結論:
- トライエチルメチラモニウムテトラブロモフェラート (TETRABROMOFERATE) は,室温以上の分子マルチフェロリックスに有望な候補である.
- 室温に近い強力な磁気流電結合は,センサーやメモリデバイスでの応用の可能性を強調しています.
- 物質の複雑な相変化の振る舞いは,さらなる調査を要する.
関連する概念動画
Ferromagnetism
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
Paramagnetism
Paramagnets are materials with unpaired electrons that possess a finite magnetic moment. In the absence of a magnetic field, these moments are randomly oriented, and thus the net moment is zero. Under an external field, a torque acting on the moments tends to align them along the field's direction. However, the random thermal motion of electrons produces a torque opposite to the external field and tries to disorient the moments. These two competing effects align only a few moments along the...
Diamagnetism
Materials consisting of paired electrons have zero net magnetic moments. However, when these materials are placed under an external magnetic field, the moments opposite to the field are induced. Such materials are called diamagnets. Diamagnetism is the response of the diamagnets when placed in an external magnetic field.
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets.
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets.
Colors and Magnetism
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
Valence Bond Theory
Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
Crystal Field Theory - Octahedral Complexes
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...

