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B-ヘテロサイクルのπ-ラジカルと,ボリルラジカルとしてのその反応性の合成と特徴付け

Yoshitaka Aramaki1, Hideki Omiya, Makoto Yamashita

  • 1Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.

Journal of the American Chemical Society
|December 5, 2012
PubMed
まとめ

研究者らは,最初の安定したダイアザボラサイクルの中性基を報告した. ESRとDFTによって特徴づけられるこの赤色のラジカルは,位置外電子を発現し,ボリルラジカルとして反応する.

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