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Updated: May 15, 2026

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)
06:34

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)

Published on: June 20, 2014

金属-炭素結合に酸素原子を挿入するための可変経路:Cp*W(O) 2(CH2SiMe3) のケース

Jiajun Mei1, Kurtis M Carsch, Cody R Freitag

  • 1Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904-4319, United States.

Journal of the American Chemical Society
|December 25, 2012
PubMed
まとめ

オーガノメタリック複合体Cp*W(O)(2)(CH(2)SiMe(3)) は,酸素ドナーと反応してトリメチルシリルメタノールを形成する. ペリオデートと過酸化水素で異なる反応経路が観察され,リガンドの移動とプロトノリシスを含む.

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