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Updated: May 15, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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イリジウム-メチル結合の水素分解のメカニズム:メタン複合体の中間物質の証拠

Jesús Campos1, Sabuj Kundu, Dale R Pahls

  • 1Departamento de Química Inorgánica, Instituto de Investigaciones Químicas (IIQ), Universidad de Sevilla, Consejo Superior de Investigaciones Científicas, Avda. Américo Vespucio 49, 41092 Sevilla, Spain.

Journal of the American Chemical Society
|January 15, 2013
PubMed
まとめ

この研究は,イリジウム-メチル結合の水素分解における重要な中間物質の証拠を提供します. A η(2) -H(2) 複合体と可逆性 σ-メタン複合体が観察され,反応機構の洞察を明らかにした.

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