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Updated: May 13, 2026

Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyl(tropone)iron
07:56

Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyl(tropone)iron

Published on: August 12, 2019

鉄触媒サイクリング反応におけるビス・イミノ・ピリジンの鉄金属サイクルの中間物質の合成と電子構造

Jordan M Hoyt1, Kevin T Sylvester, Scott P Semproni

  • 1Department of Chemistry, Princeton University, Princeton, New Jersey 08544, USA.

Journal of the American Chemical Society
|March 2, 2013
PubMed
まとめ

この研究は,リドックス活性ビス・イミノ・ピリジン・リガンドを用いた,鉄触媒サイクリング反応のための新しい触媒サイクルを明らかにしています. この発見は,以前のメカニズムの提案を修正し,鉄を強調しています.

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Pericyclic Reactions: Introduction

Pericyclic reactions are organic reactions that occur via a concerted mechanism without generating any intermediates. The reactions proceed through the movement of electrons in a closed loop to form a cyclic transition state, where rearrangement of the σ and π bonds yields specific products.
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