,C-H

Zachary D Brown1, Petra Vasko, Jeremy D Erickson

  • 1Department of Chemistry, University of California, 1 Shields Avenue, Davis, California 95616, USA.

まとめ

この研究は,メチルイソシアン化物結合と,ゲルミレンによるC-H活性化のメカニズムを詳細に説明しています. 連続した挿入とC-H活性化を明らかにし,アザゲルマサイクロペンタディエニル種を形成しています.

関連する概念動画

Cycloaddition Reactions: MO Requirements for Photochemical Activation01:12

Cycloaddition Reactions: MO Requirements for Photochemical Activation

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Benzene to 1,4-Cyclohexadiene: Birch Reduction Mechanism

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Cycloaddition Reactions: MO Requirements for Thermal Activation01:16

Cycloaddition Reactions: MO Requirements for Thermal Activation

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orthopara-Directing Activators: –CH3, –OH, –⁠NH2, –OCH3

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