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Updated: May 13, 2026

Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
07:12

Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions

Published on: July 17, 2020

ゲルミリウムイリデネルのサイクルゲルマディカルベン ("ジェルミローン") です

Yun Xiong1, Shenglai Yao, Gengwen Tan

  • 1Department of Chemistry: Metalorganics and Inorganic Materials, Technische Universität Berlin , Strasse des 17. Juni 135, Sekr. C2, D-10623 Berlin, Germany.

Journal of the American Chemical Society
|March 23, 2013
PubMed
まとめ

研究者らは,新しいゲルマニウム (((0) 複合体,循環性ゲルマディカルベンを合成し,ディカルベンのリガンドによって安定させました. このユニークな化合物は,同種の最初のもので,ゲルマニウム原子に2つの単一の電子ペアを持つ独特の電子構造を示しています.

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