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Updated: May 13, 2026

Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization
07:28

Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization

Published on: November 27, 2015

単一サイトジルコニウムアミンビスフェノラート複合体によって触媒化された1-ヘクセンポリメリゼーションのチェーン転送に対するペンダントリガンド結合親和性の効果

D Keith Steelman1, Silei Xiong, Paul D Pletcher

  • 1Brown Laboratory, Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907, USA.

Journal of the American Chemical Society
|March 23, 2013
PubMed
まとめ

この研究では,1-ヘクセンのポリメリゼーションのためのジルコニウム触媒を調査し,ペンダントリガンドの変化が反応速度とメカニズムにどのように影響するか明らかにしました. チェーン転送速度は大きく変化し,ポリマーの特性や触媒の設計に影響を及ぼした.

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