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Updated: May 13, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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3-トリメチルシリルサイクロブチリデネ. カルベネスに対するシリコンの γ 効果

Xavier Creary1

  • 1Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA. creary.1@nd.edu

Journal of the American Chemical Society
|March 27, 2013
PubMed
まとめ

3-トリメチルシリルサイクロブチリデンは,シリル移行ではなく,1,3-水素移行を経由して,1-トリメチルシリルビサイクロブチランに再構成されます. 計算分析により,この経路を好む安定したカルベンの形状が明らかになりました.

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