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Updated: May 13, 2026

Synthesis of Triazole and Tetrazole-Functionalized Zr-Based Metal-Organic Frameworks Through Post-Synthetic Ligand Exchange
04:51

Synthesis of Triazole and Tetrazole-Functionalized Zr-Based Metal-Organic Frameworks Through Post-Synthetic Ligand Exchange

Published on: June 23, 2023

小分子とカチオンのジミナルZr+/Pペアの反応

Xin Xu1, Gerald Kehr, Constantin G Daniliuc

  • 1Organisch-Chemisches Institut, Universität Münster, Corrensstrasse 40, D-48149 Münster, Germany.

Journal of the American Chemical Society
|March 27, 2013
PubMed
まとめ

新しいジルコノセーン複合体は,挫折したルイスペア (FLP) として作用し,様々な不飽和基質とのユニークなZr(+) /P加法反応を可能にします. このFLPはまた,触媒的水素化のために水素を効率的に活性化し,エノンとイノンに1,4-添加を加えます.

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