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Updated: May 12, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

オレフィンメタテシスにおけるRu-インデニリデネ複合体の活性化機構

César A Urbina-Blanco1, Albert Poater, Tomas Lebl

  • 1EaStCHEM School of Chemistry, University of St. Andrews, North Haugh, St. Andrews, Fife, United Kingdom.

Journal of the American Chemical Society
|April 27, 2013
PubMed
まとめ

ルテニウム触媒は,炭素-炭素二重結合を作るための重要な反応であるオレフィン転移を駆動します. この研究は,異なるルテニウム複合体,特にインデニリデンおよびベンジリデン型が,異なるメカニズムを通じて反応を開始し,以前の仮定に異議を唱えることを示しています.

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