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Updated: May 11, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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銅二酸化窒素によるC-Hアミネーションの仕組みに関する洞察

Mae Joanne B Aguila1, Yosra M Badiei, Timothy H Warren

  • 1Department of Chemistry, Georgetown University, Box 571227-1227, Washington, DC 20057, United States.

Journal of the American Chemical Society
|May 10, 2013
PubMed
まとめ

銅アルキルニトロンの中間物質は,C-Hアミネーション反応の鍵となります. 研究によると,ターミナルナイトレンは活性種であり,段階的なH原子抽出とラジカルリバウンドメカニズムを経由して進行しています.

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