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Updated: May 11, 2026

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
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ニオビウム (III) イミド複合体によって媒介されたベンジル基CF3群の分解

Thomas L Gianetti1, Robert G Bergman, John Arnold

  • 1Department of Chemistry, University of California, Berkeley , California 94720, United States.

Journal of the American Chemical Society
|May 14, 2013
PubMed
まとめ

ニオビウムイミド複合体は,CF3領域の3つのC-F結合をすべて活性化し,強いニオビウム-フッ化物結合を形成する. この反応メカニズムはニオビウム (III) を含み,非芳香的CF3群とのユニークな分子内反応性を示しています.

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