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Updated: May 11, 2026

Microscopic Visualization of Porous Nanographenes Synthesized through a Combination of Solution and On-Surface Chemistry
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グラフェンの低温ボトムアップ合成は,ラジカルカップリング反応によるものです

Lang Jiang1, Tianchao Niu, Xiuqiang Lu

  • 1Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.

Journal of the American Chemical Society
|May 25, 2013
PubMed
まとめ

研究者らは,軽度の根幹結合反応を用いた低温グラフェン合成方法を開発した. この技術は,220~250°Cでヘクサブロムベンゼン前駆体から高品質のグラフェンフィルムを効率的に生成します.

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Radicals, the highly reactive species, gain stability by undergoing three different reactions. The first reaction involves a radical-radical coupling, in which a radical combines with another radical, forming a spin‐paired molecule. The second reaction is between a radical and a spin‐paired molecule, generating a new radical and a new spin‐paired molecule. The third reaction is radical decomposition in a unimolecular reaction, forming a new radical and a spin‐paired molecule. These three...
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Similar to charge conservation in chemical reactions, spin conservation is implicit for radical reactions. Accordingly, the product formed must possess an unpaired...
Radical Formation: Overview01:03

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Radicals can be obtained from spin-paired molecules either by homolysis or electron transfer. While two radicals are formed in the former, an electron is added in the latter, also known...
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