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Updated: May 10, 2026

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
07:14

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers

Published on: May 12, 2023

主群の分子における分散力と反直感的なステリック効果:より重量のあるグループ14 (Si-Pb) の二カルコゲノレートカルベンの同類体で,90°未満のインターリガンド結合角度を持つ

Brian D Rekken1, Thomas M Brown, James C Fettinger

  • 1Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California, 95616, USA.

Journal of the American Chemical Society
|June 4, 2013
PubMed
まとめ

研究者らは,異常に鋭い結合角度を持つテトリレン二カルコゲノラートを合成した. これらの角度は,ステリック的な期待に反して,リガンドのサイズが増加するにつれて狭くなり,分散力によって安定します.

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