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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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N-フッ素ベンゼンスルフォニミドを用いたアルケンのエナチオセレクティブパラジウム触媒ダイアミネーション

Erica L Ingalls1, Paul A Sibbald, Werner Kaminsky

  • 1Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, USA.

Journal of the American Chemical Society
|June 6, 2013
PubMed
まとめ

この研究では,アルケンのエナチオセレクティブのパラジウム触媒による近隣ダイアミネーションを導入しています. N-fluorobenzenesulfonimideを用いて,高いエナチオ選択性を持つ微分保護された近隣ダイアミンを効率的に生成します.

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