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Updated: May 10, 2026

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
07:36

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

Published on: November 9, 2019

エナチオセレクティブカルベン触媒による無効化のための二重ルイス塩基活性化戦略

Javier Izquierdo1, Ane Orue, Karl A Scheidt

  • 1Department of Chemistry, Center for Molecular Innovation and Drug Discovery, Chemistry of Life Processes Institute, Northwestern University, Silverman Hall, Evanston, Illinois 60208, USA.

Journal of the American Chemical Society
|July 9, 2013
PubMed
まとめ

研究者は,N-ヘテロサイクリックカルベン (NHC) カタリシスとルイス塩基活性化を用いた二重活性化戦略を開発しました. この方法は,α,β-不飽和アルデヒドおよびo-キノンメチドから,2-ベンゾキソピノンをエナンチオセレクティブに合成します.

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α-Alkylation of Ketones via Enolate Ions

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