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関連する概念動画

Paramagnetism01:30

Paramagnetism

Paramagnets are materials with unpaired electrons that possess a finite magnetic moment. In the absence of a magnetic field, these moments are randomly oriented, and thus the net moment is zero. Under an external field, a torque acting on the moments tends to align them along the field's direction. However, the random thermal motion of electrons produces a torque opposite to the external field and tries to disorient the moments. These two competing effects align only a few moments along the...
Ferromagnetism01:31

Ferromagnetism

Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
Magnetic Susceptibility and Permeability01:31

Magnetic Susceptibility and Permeability

In linear magnetic materials, like paramagnets and diamagnets, magnetization is proportional to the magnetic field intensity. The constant of proportionality, a dimensionless number, is called magnetic susceptibility. The value of the susceptibility depends on the type of material.
When diamagnetic materials are placed under an external magnetic field, the moments opposite to the field are induced. Hence, the susceptibility for diamagnets has a minimal negative value of 10-5–10-6. Since...
Diamagnetism01:26

Diamagnetism

Materials consisting of paired electrons have zero net magnetic moments. However, when these materials are placed under an external magnetic field, the moments opposite to the field are induced. Such materials are called diamagnets. Diamagnetism is the response of the diamagnets when placed in an external magnetic field.
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets.
Colors and Magnetism03:02

Colors and Magnetism

Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
Types of Reversible Electrodes01:24

Types of Reversible Electrodes

For electrode reversibility to be maintained, all the reactants and products involved in the half-reaction must be present at the electrode. There are several types of reversible electrodes (half-cells).In metal-metal-ion electrodes, a metal balances electrochemically with a solution of its own ions. Examples are Cu2+|Cu and Zn2+|Zn. Metals that react with the solvent, like group 1 and most group 2 metals, which react with water, and zinc, which reacts with aqueous acidic solutions, cannot be...

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関連する実験動画

Updated: May 10, 2026

Paramagnetic Relaxation Enhancement for Detecting and Characterizing Self-Associations of Intrinsically Disordered Proteins
07:24

Paramagnetic Relaxation Enhancement for Detecting and Characterizing Self-Associations of Intrinsically Disordered Proteins

Published on: September 23, 2021

水中の非共振的に反転可能なパラマグネットスイッチ.

Alexander T Buck1, Joseph T Paletta, Shalika A Khindurangala

  • 1Department of Chemistry, Iowa State University, Ames, Iowa 50011, USA.

Journal of the American Chemical Society
|July 9, 2013
PubMed
まとめ

研究者らは,ビス・ビオロゲン・ダイラジカルを用いたオルゴ・パラマグネットスイッチを開発した. この分子は,キュキュルビット[7]ウリルを用いて水中の磁気状態を逆転的に変化させ,新しい電子とセンサーのアプリケーションを可能にします.

科学分野:

  • 超分子化学 超分子化学
  • マテリアルサイエンス 材料科学
  • オーガニック・エレクトロニクス

背景:

  • 切り替え可能な磁気材料の開発は,先進技術にとって極めて重要です.
  • ヴィオロゲンベースのラジカルシステムは,磁気特性制御の可能性を秘めています.
  • ゲスト-ホスト化学は,分子スイッチングのためのプラットフォームを提供します.

研究 の 目的:

  • 新しい有機パラマグネットスイッチの設計と特徴付け.
  • 非共振相互作用を用いた可逆磁気状態サイクルを実証する.
  • スイッチ可能な磁気分子の潜在的な応用を探求する.

主な方法:

  • リンクされたbis ((viologen) dication dirradical.の合成でした.
  • キュキュルビット[7]ウリル (CB[7]) とのゲストホスト複合性の調査.
  • 水溶液における磁性特性の特徴.
  • ラジカル相互作用のコンピューティングモデリング.

主要な成果:

  • ビス (ビオロゲン) ダイラジカルが合成され,オルガノパラマグネティックスイッチとして作用することが示されました.

さらに関連する動画

Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy
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Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy

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Aqueous Droplets Used as Enzymatic Microreactors and Their Electromagnetic Actuation
08:27

Aqueous Droplets Used as Enzymatic Microreactors and Their Electromagnetic Actuation

Published on: August 28, 2017

関連する実験動画

Last Updated: May 10, 2026

Paramagnetic Relaxation Enhancement for Detecting and Characterizing Self-Associations of Intrinsically Disordered Proteins
07:24

Paramagnetic Relaxation Enhancement for Detecting and Characterizing Self-Associations of Intrinsically Disordered Proteins

Published on: September 23, 2021

Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy
10:28

Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy

Published on: May 27, 2018

Aqueous Droplets Used as Enzymatic Microreactors and Their Electromagnetic Actuation
08:27

Aqueous Droplets Used as Enzymatic Microreactors and Their Electromagnetic Actuation

Published on: August 28, 2017

  • ダイア磁性状態とパラ磁性状態の間の可逆的な切り替えは,水中のCB [7] 複合化によって達成されました.
  • 計算分析により,バイオゲン基幹単位間のパイダイマー (パイマー) 相互作用が示されました.
  • 結論:

    • この研究は,水に調節可能な磁気特性を持つ新しい分子スイッチを提示しています.
    • この発見は,スピントロニクス,データストレージ,化学センサーへの道を開く.
    • 開発されたシステムは,高度な磁気材料と探査機の構成要素として機能します.