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Updated: May 9, 2026

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
05:48

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Published on: November 21, 2017

ポリフタルアルデヒドのエンドグループの特徴付け:可逆性のあるカチオンのマクロサイクリング機構の驚くべき発見

Joshua A Kaitz1, Charles E Diesendruck, Jeffrey S Moore

  • 1Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA.

Journal of the American Chemical Society
|August 9, 2013
PubMed
まとめ

オフタラアルデヒドのカチオンのポリメリゼーションにより,高純度な循環型ポリフタラアルデヒド (PPA) が得られます. この周期的なPPAは,独特の反転可能なリング開きとチェーン延長特性を示し,ポリマー合成の柔軟性とリトグラフィーの可能性を提供します.

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