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Updated: May 9, 2026

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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Fe触媒によるα-アリルアルデヒドの地域変異 [1,2]-シフト

Álvaro Gutiérrez-Bonet1, Areli Flores-Gaspar, Ruben Martin

  • 1Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain.

Journal of the American Chemical Society
|August 10, 2013
PubMed
まとめ

鉄の触媒は[1,2]シフトの再編成によってアルデヒドからケトンへの変換を可能にします. この骨格の再編成は,電子効果によって制御される,アーリルまたはアルキルシフトのための幅広い基板範囲と調節可能な選択性を提供します.

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