エタン,プロパン,C4-C8の線形アルカン,およびチタン-炭素の多重結合によるいくつかの周期性アルカンの室温脱水

Marco G Crestani1, Anne K Hickey, Xinfeng Gao

  • 1Department of Chemistry, Indiana University , Bloomington, Indiana 47405, United States.

まとめ

この研究は,一時的なチタンのノエペンチリジンの複合体が,線形アルケンを効率的に脱水させ,アルファ-オレフィン複合体を形成することを示しています. これらの複合体はさらに機能化され,または自由オレフィンを放出することができ,有機金属化学における多用途の反応性を示します.

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