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Updated: May 8, 2026

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
05:48

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Published on: November 21, 2017

Zn ((C6F5) 2) ベースのルイスペアによるリング開きポリメリゼーション:サイクルポリエステルのオリジナルで効率的なアプローチ

Estefanía Piedra-Arroni1, Catherine Ladavière, Abderrahmane Amgoune

  • 1Laboratoire Hétérochimie Fondamentale et Appliquée, UMR CNRS 5069, Université de Toulouse , F-31062 Toulouse, France.

Journal of the American Chemical Society
|August 31, 2013
PubMed
まとめ

亜鉛と有機塩基を用いた二重触媒システムは,乳酸塩とカプロラクトンの制御されたポリメリゼーションを可能にします. この方法により,高分子量サイクルポリエステルとサイクルブロックコポリマーが作られます.

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