高いステレオ選択性と (塩) Co (III) 触媒化水解運動解像度の広い基板範囲のメカニズム的基礎

David D Ford1, Lars P C Nielsen, Stephan J Zuend

  • 1Department of Chemistry and Chemical Biology, Harvard University , Cambridge, Massachusetts 02138, United States.

PubMed
まとめ

コバルト (III) 複合物を用いたエポキシドの水解運動分辨率 (HKR) は,バイメタリックメカニズムを通じて高いステレオ選択性を達成します. この研究は,ステレオ化学的コミュニケーションがサレンのリガンドによって媒介されていることを明らかにしています.

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