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Updated: May 7, 2026

Synthetic Methodology for Asymmetric Ferrocene Derived Bio-conjugate Systems via Solid Phase Resin-based Methodology
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Synthetic Methodology for Asymmetric Ferrocene Derived Bio-conjugate Systems via Solid Phase Resin-based Methodology

Published on: March 12, 2015

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軸性キラルヘテロバイアリルシールの非対称合成のためのダイナミック・キネティック・クロスカップリング戦略

Abel Ros1, Beatriz Estepa, Pedro Ramírez-López

  • 1Instituto Investigaciones Químicas (CSIC-US), University of Seville , C/Américo Vespucio, 49, 41092 Sevilla, Spain.

Journal of the American Chemical Society
|October 11, 2013
PubMed
まとめ

新しいダイナミック・キネティック・アシンメトリック・トランスフォーメーション (DYKAT) 方法により,キラルピリジンとイソキノリンを合成する. このパラジアム触媒による結合は,ラセミックな起始材料を用いて,価値あるヘテロビアリル化合物の高いエナチオセレクティブ性を達成する.

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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