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Updated: May 6, 2026

Solid-phase Synthesis of [4.4] Spirocyclic Oximes
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モジュールメゾイオニクス: ミュンクノンの誘導体の1,3-二極サイクロアディションにおける地域選択性を理解し制御する

Marie S T Morin1, Daniel J St-Cyr, Bruce A Arndtsen

  • 1Department of Chemistry, McGill University , 801 Sherbrooke Street West, Montréal, Quebec H3A 2K6, Canada.

Journal of the American Chemical Society
|October 19, 2013
PubMed
まとめ

ミュンクノーンやフォスファ-ミュンクノーンなどのメソイオン1,3-二極体は,ピロールのモジュール合成を提供します. アルキンとのサイクロアディションにおけるそれらの反応性と地域選択性は,アルキン電子と移行状態エネルギーによって制御されます.

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