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Updated: May 6, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

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触媒的なC-H/C-Oバイアリル結合におけるアリルニッケル (II) ピヴァラート複合体の分離,構造,および反応性

Kei Muto1, Junichiro Yamaguchi, Aiwen Lei

  • 1Institute of Transformative Bio-Molecules (WPI-ITbM) and Graduate School of Science and §JST, ERATO, Itami Molecular Nanocarbon Project, Nagoya University , Nagoya 464-8602, Japan.

Journal of the American Chemical Society
|October 25, 2013
PubMed
まとめ

この研究では,1,3-アゾールとアリルピヴァラトのニッケル触媒C-H/C-Oビアリル結合の詳細が示されています. 機械学的調査は,C-Hニッケル化が触媒サイクルにおける速度制限ステップであることを明らかにした.

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