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Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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Pd (II) によるフッ化ホルムの核愛性触媒による容易かつ高度に選択的なC-H活性化である

Shin Takemoto1, Vladimir V Grushin

  • 1Institute of Chemical Research of Catalonia (ICIQ) , Tarragona 43007, Spain.

Journal of the American Chemical Society
|October 31, 2013
PubMed
まとめ

この研究は,室温でH-CF3の活性化のための簡単な方法を提示し,パラジウム-トリフルオロメチル (Pd-CF3) 結合を形成します. 水素結合とルイス塩基促進を含む新しいメカニズムが提案されています.

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