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Dissolution Dynamic Nuclear Polarization Instrumentation for Real-time Enzymatic Reaction Rate Measurements by NMR
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メチル群の長寿命の核スピン状態と量子回転器誘発の極化

Benno Meier1, Jean-Nicolas Dumez, Gabriele Stevanato

  • 1School of Chemistry, University of Southampton , SO17 1BJ Southampton, U.K.

Journal of the American Chemical Society
|November 21, 2013
PubMed
まとめ

急速に回転するメチル基は,溶液中の長寿命状態 (LLS) を可能にし,リラックス時間を延長します. (13) C-γ-ピコリンで観察されたこの現象は,ハイパーポラライズされたLLSを通じて強化されたNMR信号を説明します.

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