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Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
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カーベンの可逆挿入により,ルテニウム-シリコン結合にカーベンが挿入される

María J Bernal1, Olga Torres, Marta Martín

  • 1Instituto de Sı́ntesis Quı́mica y Catálisis Homogénea (ISQCH), CSIC-Universidad de Zaragoza , E-50009 Zaragoza, Spain.

Journal of the American Chemical Society
|December 3, 2013
PubMed
まとめ

新しいルテニウムカルベンの複合体は,Grubbs触媒に類似しており,ユニークな反応性を表しています. カーベンのリガンドはRu-Si結合に挿入し,C-H機能化やアルキンの挿入などの多様な変換を可能にします.

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