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The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique
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ポリオキソメタラート触媒による酸素の挿入は,O(2) からチン-アルキル結合に挿入されます

Alexander M Khenkin1, Irena Efremenko, Jan M L Martin

  • 1Department of Organic Chemistry, Weizmann Institute of Science , Rehovot, Israel 76100.

Journal of the American Chemical Society
|December 10, 2013
PubMed
まとめ

ポリオキソメタラートH5PV2Mo10O40は,電子移転により,チン-炭素結合を活性化し,1-ブタノールと (n-Bu3Sn) 2O.を生成する. この反応は分子酸素で触媒作用を行い,オルガノチン化合物の変換のための新しい経路を提供します.

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