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Updated: May 5, 2026

Millisecond Hydrogen/Deuterium-Exchange Mass Spectrometry for the Study of Alpha-Synuclein Structural Dynamics Under Physiological Conditions
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Millisecond Hydrogen/Deuterium-Exchange Mass Spectrometry for the Study of Alpha-Synuclein Structural Dynamics Under Physiological Conditions

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ディヒドロサピリン同位体のマクロサイクル収縮と膨張

Yongshu Xie1, Pingchun Wei, Xin Li

  • 1Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology , Shanghai 200237, P. R. China.

Journal of the American Chemical Society
|December 10, 2013
PubMed
まとめ

研究者らは,ユニークなピロール変異を調査し,ダイヒドロサピリンやイソスマルガディリン類のような新しいマクロサイクルを作成しました. ある化合物の亜鉛複合体は近赤外線放射を示し,新しい化学経路を示した.

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Stability of Conjugated Dienes01:28

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The Cope rearrangement is classified as a [3,3] sigmatropic shift in 1,5-dienes, leading to a more stable, isomeric 1,5-diene. The reaction involves a concerted movement of six electrons, four from two π bonds and two from a σ bond, via an energetically favorable chair-like transition state.
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