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なぜ (SiO) ((4) は四面体として計算され, (CO) ((4) は正方形の平面体であるのでしょうか? 分子軌道分析によるものです

Sebastian Kozuch1, David A Hrovat, Weston Thatcher Borden

  • 1Department of Chemistry and Center for Advanced Scientific Computing and Modeling (CASCaM), University of North Texas , Denton, TX 76201, United States.

Journal of the American Chemical Society
|December 17, 2013
PubMed
まとめ

(SiO) 4と (SiS) 4のようなテトラサイクロブタン化合物は,炭素同類物とは異なり,三重基底状態の四面体構造を好みます. この幾何学の好みは,Jahn-Teller効果によって説明されるように,電子陰性差によって影響を受けます.

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