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Updated: May 4, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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sp3-sp2 vs sp3-sp3 ベンゾサイクロブテノールのRh触媒によるリング開封におけるC-C部位選択性:DFT研究

Lina Ding1, Naoki Ishida, Masahiro Murakami

  • 1Fukui Institute for Fundamental Chemistry, Kyoto University , Kyoto 606-8103, Japan.

Journal of the American Chemical Society
|December 18, 2013
PubMed
まとめ

ベンゾサイクロブテノールのRh触媒によるリング開きは,移行状態の安定化によるC(sp(3)) -C(sp(2)) 結合割れを好みます. この重要なC−C結合活性化プロセスにおいて,溶媒の極性とリガンドの大量の影響がサイト選択性に影響します.

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