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Updated: May 4, 2026

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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C60への [3 + 2] サイクル添加によるキラルフルレンのステレオダイバーゲント合成

Enrique E Maroto1, Salvatore Filippone, Margarita Suárez

  • 1Departamento de Química Orgánica I, Facultad de Química, Universidad Complutense , E-28040 Madrid, Spain.

Journal of the American Chemical Society
|December 24, 2013
PubMed
まとめ

新しい触媒は,1,3-二極サイクロアディションを介して,ピロリディノ[60]フルレンのステレオダイバージェント合成を可能にします. チラルイミノアミドは二重非対称的誘導を誘導し,エナチオセレクティブのレトロサイクロアディションの可能性があります.

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