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Updated: May 4, 2026

A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis
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A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis

Published on: February 16, 2020

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アリルシランとアレンの金触媒酸化結合:選択性の起源と改良された前触媒

Liam T Ball1, Guy C Lloyd-Jones, Christopher A Russell

  • 1School of Chemistry, University of Edinburgh , Joseph Black Building, West Mains Road, Edinburgh EH9 3JJ, U.K.

Journal of the American Chemical Society
|December 26, 2013
PubMed
まとめ

ゴールド・カタリシスにより,AU (I) /AU (III) レドックスサイクルを通じて,シランと選択的アレン結合が可能になります. このメカニズムは,合成化学において極めて重要なヘテロカップリング反応における高い選択性を説明する.

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