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Updated: May 4, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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ロジウム触媒によるプロパルギルCH活性化のメカニズム調査

Urs Gellrich1, Antje Meißner, Alberto Steffani

  • 1Institut für Organische Chemie, Albert-Ludwigs-Universität , 79104 Freiburg, Germany.

Journal of the American Chemical Society
|January 1, 2014
PubMed
まとめ

この研究は,ロジウム触媒によるアルキン-カルボキシル酸結合の新しいメカニズムを明らかにし,分子内プロトネーション経路と独特の σ-アリル複合体を触媒の静止状態として特定しました.

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