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Updated: May 4, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

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アリルハリドの非対称な分子間ヘック反応

Chunlin Wu1, Jianrong Steve Zhou

  • 1Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University , 21 Nanyang Link, Singapore 637371.

Journal of the American Chemical Society
|January 4, 2014
PubMed
まとめ

この研究は,アリルおよびビニルブロミドに対する非対称な分子間ヘック反応を拡張し,サイクルオレフィンで高いエナチオセレクティビティを達成しました. 新種のスパイロ脊椎ビスホスフィン酸化物は,高度にステレオ選択性の高いパラジウム触媒を可能にしました.

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