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Updated: May 4, 2026

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
10:42

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV

Published on: December 29, 2016

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Sr-Pb-Sシステムにおける異常な三位式の有序半導体化合物の理論的予測と実験的確認

Shiqiang Hao1, Li-Dong Zhao, Chang-Qiang Chen

  • 1Department of Materials Science & Engineering, and ‡Department of Chemistry, Northwestern University , Evanston, Illinois 60208, United States.

Journal of the American Chemical Society
|January 9, 2014
PubMed
まとめ

CaPbSでは相分離が好ましいが,SrPbS系には,SrPb3S4のような安定した,秩序のある三元化合物が存在する. この研究は,理論と実験を組み合わせて,複雑な半導体合金相関係を理解します.

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Electron configurations and orbital diagrams can be determined by applying the Aufbau principle (each added electron occupies the subshell of lowest energy available), Pauli exclusion principle (no two electrons can have the same set of four quantum numbers), and Hund’s rule of maximum multiplicity (whenever possible, electrons retain unpaired spins in degenerate orbitals).
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Consider a ternary system, which is composed of three components: water (W), ethanoic acid (E), and trichloromethane (T). Here, Ethanoic acid (E) is fully miscible with both water (W) and trichloromethane (T), meaning it can mix entirely with either of them. However, water and trichloromethane have partial miscibility, meaning they can only mix to a certain extent, beyond which two separate phases will form.The phase diagram of a ternary system is represented as an equilateral triangle, where...
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