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Updated: May 3, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

Published on: April 19, 2019

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コバルト-コバルト結合を2つの周期性アルキルアミノカルベンによって安定させる

Kartik Chandra Mondal1, Prinson P Samuel, Herbert W Roesky

  • 1Institut für Anorganische Chemie, Georg-August-Universität , Tammannstraße 4, 37077 Göttingen, Germany.

Journal of the American Chemical Society
|January 21, 2014
PubMed
まとめ

この研究では,新型のコバルト-カルベン複合体 (Me2-cAAC:) 2Co2) を合成し,酸化状態がゼロのコバルトを合成した. 複合体はシングレット基底状態を示し,可逆性還元酸化反応を経て,酸化状態で顕著なCo-Co結合の縮小を伴う安定した根性イオンを形成します.

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