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Updated: May 3, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

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ニッケル触媒による非活性化C ((sp3) -H結合のサイト選択性アルキル化

Xuesong Wu1, Yan Zhao, Haibo Ge

  • 1Department of Chemistry and Chemical Biology, Indiana University Purdue University Indianapolis , Indianapolis, Indiana 46202 United States.

Journal of the American Chemical Society
|January 23, 2014
PubMed
まとめ

ニッケル触媒は,アリファティックアミドの活性化されていない sp (3) C-H 結合を直接アルキル化します. この方法はメチル基よりもメチル基を優先的に標的とし,効率的な化学合成のための幅広い機能群耐性を示しています.

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