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キラルリチウムアミド集積物に対するステリック因子の影響

Chicheung Su1, Russell Hopson, Paul G Williard

  • 1Department of Chemistry, Brown University , 324 Brook Street, Providence, Rhode Island 02912 United States.

Journal of the American Chemical Society
|January 24, 2014
PubMed
まとめ

キラルリチウムアミドにおけるステリック阻害は,n-ブチルリチウムとの結合状態を決定する. 阻害が少ないアミドは2:2アグリゲットを形成し,ステリック量が増えたアグリゲットは2:1混合アグリゲットを好み,溶液構造に影響を与えます.

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