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超臨界二酸化炭素を用いた選択的自由基反応

Philip J Cormier1, Ryan M Clarke, Ryan M L McFadden

  • 1Department of Chemistry and Biochemistry, Mount Allison University , 63C York Street, Sackville, New Brunswick E4L 1G8, Canada.

Journal of the American Chemical Society
|January 31, 2014
PubMed
まとめ

研究者は,超臨界の二酸化炭素を用いてアルケンの反応性を修正した. この溶媒は非極性反応剤との反応を調節し,臨界点近くのエチレンとハロゲンアルケンの効果が異なる.

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