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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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線形アルデヒドのステレオ変異性α-アライレーションは,二重イリジウムとアミンの触媒による

Simon Krautwald1, Michael A Schafroth, David Sarlah

  • 1Eidgenössische Technische Hochschule Zürich , 8093 Zürich, Switzerland.

Journal of the American Chemical Society
|February 11, 2014
PubMed
まとめ

この研究では,イリジウムを用いたアルデヒドのステレオ選択的アリレーションのための新しい二重触媒法が導入されています. このアプローチにより,抗うつ薬パロキセチンを含む複雑な分子の効率的な合成が可能になります.

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