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Updated: May 2, 2026

A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones
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A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones

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イソニトリルのクロム媒介的還元結合により,珍しいヘテロサイクルが形成されます

Jingmei Shen1, Glenn P A Yap, Klaus H Theopold

  • 1Department of Chemistry and Biochemistry, University of Delaware , Newark, Delaware 19716, United States.

Journal of the American Chemical Society
|February 21, 2014
PubMed
まとめ

クロミウムジメは,サイクロヘキシルイソシアン酸を還元的にカップル化し,新しい窒素ヘテロサイクルを形成します. これらの反応により,芳香性スクワラミダニネットとダイアザ-ビサイクロ[3.3.0]オクタディエンの構造が生み出され,合成の有用性を提供します.

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