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Reaction Kinetics and Combustion Dynamics of I4O9 and Aluminum Mixtures
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酸素原子を半サンドイッチのイリジウム複合体に移す:クリーンな酸化により分子産物が生じる

Christopher R Turlington1, Peter S White, Maurice Brookhart

  • 1W. R. Kenan Laboratory, Department of Chemistry, University of North Carolina at Chapel Hill , Chapel Hill, North Carolina 27599-3290, United States.

Journal of the American Chemical Society
|February 28, 2014
PubMed
まとめ

イリジウム複合体は酸化中に2つの酸素原子移転 (OAT) イベントを経験し,新しい中間物質と酸化されたイリジウム種を形成します. この酸化複合体は,酸素をフォスフィンに転送し,フォスフィン酸化物とIr-PPh3誘導体を生成します.

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