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Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides CHIPS
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Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides CHIPS

Published on: June 20, 2014

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イミダゾールとアロマティックおよびベンジル化合物の直接的なC-N結合は,電酸化C-H機能化によるものです

Tatsuya Morofuji1, Akihiro Shimizu, Jun-ichi Yoshida

  • 1Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University , Nishikyo-ku, Kyoto 615-8510, Japan.

Journal of the American Chemical Society
|March 15, 2014
PubMed
まとめ

新しい電酸化C-H機能化の方法により,イミダゾールの効率的なC-N結合が可能になる. このアプローチは,保護されたイミダゾリウムイオンを形成することにより,過剰酸化を回避し,多様なN置換イミダゾールを生成します.

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