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チオラートリガンドは,CeO2でCO酸化のための両刃の剣として,Au25 (((SCH2CH2Ph) 18ナノクラスターをサポートするCeO2でCO酸化を行う

Zili Wu1, De-en Jiang, Amanda K P Mann

  • 1Chemical Science Division, ‡Center for Nanophase Materials Sciences, and §Materials Science and Technology Division, Oak Ridge National Laboratory , Oak Ridge, Tennessee 37831, United States.

Journal of the American Chemical Society
|April 8, 2014
PubMed
まとめ

金ナノクラスターのチオラートリガンドは,最初はCO吸収を阻害しますが,除去すると活性部位が露出し,CeO2棒のCO酸化触媒を強化します. カチオンの金鉱跡は,低温反応に不可欠である.

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